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Beilstein J. Org. Chem. 2024, 20, 436–444, doi:10.3762/bjoc.20.38
Graphical Abstract
Figure 1: Structures of a) [10]CPP⊃C60, (b) [n+5]CPP⊃[n]CPP, and (c) [10]CPP⊃[5]CPP2+ (this work).
Figure 2: 1H NMR spectra (CD2Cl2, 25 °C) of a) a mixture of [8]–[12]CPPs and [5]CPP2+[B(C6F5)4−]2 before and aft...
Figure 3: Cyclic voltammograms of [10]CPP⊃[5]CPP2+[B(C6F5)4−]2, [10]CPP, and [5]CPP2+[B(C6F5)4−]2 in Bu4N+ B(C...
Figure 4: UV–vis–NIR spectra of [10]CPP⊃[5]CPP2+[B(C6F5)4−]2 (black), [10]CPP (blue), and [5]CPP2+[B(C6F5)4−]2...
Figure 5: Top and side view of [10]CPP⊃[5]CPP2+ complexes a) 1, b) 2, and c) 3 obtained by DFT calculation at...
Figure 6: HOMO−1, HOMO, LUMO, and LUMO+1 orbitals of [10]CPP⊃[5]CPP2+ (1), [5]CPP2+, and [10]CPP.
Figure 7: X-ray crystal structure of [10]CPP⊃[5]CPP2+[B(C6F5)4]2. a) Side and b) top views of ORTEP drawings....